Coordination of the ambiphilic phosphinoborane tBu2PCH2BPh2 to Cu(I)Cl
| Authors |
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| Publication date | 11-2017 |
| Journal | Zeitschrift für Naturforschung. B, A Journal of Chemical Sciences |
| Volume | Issue number | 72 | 11 |
| Pages (from-to) | 781-784 |
| Number of pages | 4 |
| Organisations |
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| Abstract | A chloro-bridged dimeric copper(I) complex with the ambiphilic phosphinoborane ligand tBu2PCH2BPh2 is reported. The molecular structure was determined by single-crystal X-ray diffraction analysis, revealing a secondary η1-C interaction of the ligand with the metal center. The complex exhibits green fluorescence when exposed to UV light at 366 nm. |
| Document type | Article |
| Language | English |
| Related dataset | CCDC 1548516: Experimental Crystal Structure Determination |
| Published at | https://doi.org/10.1515/znb-2017-0078 |
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