Tellurium(II)/Tellurium(III)-Catalyzed Cross-Dehydrogenative C-N Bond Formation

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Authors
Publication date 15-03-2021
Journal Angewandte Chemie, International Edition
Volume | Issue number 60 | 12
Pages (from-to) 6451-6456
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract The Te-II/Te-III-catalyzed dehydrogenative C-H phenothiazination of challenging phenols featuring electron-withdrawing substituents under mild aerobic conditions and with high yields is described. These unexpected Te-II/Te-III radical catalytic properties were characterized by cyclic voltammetry, EPR spectroscopy, kinetic experiments, and DFT calculations.
Document type Article
Language English
Related publication Tellur(II)/Tellur(III)-katalysierte dehydrierende C-N-Bindungsbildung
Published at https://doi.org/10.1002/anie.202015248 https://doi.org/10.1002/ange.202015248
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