Resonance-enhanced multiphoton ionization photoelectron spectroscopy of Rydberg states of N<sub>2</sub>O below the X<sup>2</sup>Π ionization limit

Resonance-enhanced multiphoton ionization photoelectron spectroscopy of Rydberg states of N₂O below the X²Π ionization limit

Authors	C.R. Scheper J. Kuijt W.J. Buma C.A. de Lange
Publication date	1998
Journal	Journal of Chemical Physics
Volume \| Issue number	109 \| 18
Pages (from-to)	7844-7850
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract	A three-photon resonance-enhanced multiphoton ionization spectroscopic study on N2O is carried out in the spectral range from 80 000 cm - 1 up to the lowest ionization limit at 103 963 cm - 1. High-resolution photoelectron spectroscopy is used to identify and characterize the observed excited states. Eighteen origins are reported which have either not been assigned before or are reassigned now. Moreover, the photoelectron spectra taken at higher-lying resonances often show extensive vibronic coupling with the near-resonant vibronic manifolds built on lower-lying origins.
Document type	Article
Language	English
Published at	https://doi.org/10.1063/1.477431
Downloads	JChPh_1998_109-18_7844.pdf (Final published version)
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