Ligands that Store and Release Electrons during Catalysis
| Authors | |
|---|---|
| Publication date | 04-04-2011 |
| Journal | Angewandte Chemie, International Edition |
| Volume | Issue number | 50 | 15 |
| Pages (from-to) | 3356-3358 |
| Number of pages | 3 |
| Organisations |
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| Abstract | Electron(ic) banking : First‐row transition metals can be given a noble character by redox‐active ligands, thus enabling two‐electron oxidative addition and reductive elimination steps (see scheme). A recently reported cobalt‐mediated Negishi‐type cross‐coupling reaction provides an illustrative example of this concept and reveals its potential to develop new catalytic reactions with cheap, abundant metals. |
| Document type | Article |
| Language | English |
| Related publication | Liganden, die während der Katalyse Elektronen speichern und freisetzen |
| Published at |
https://doi.org/10.1002/anie.201006778
(Final published version)
https://doi.org/10.1002/ange.201006778
(Other version)
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| Permalink to this page | |
