Terpyridine complexes of Rhodium(I,III)

Thesis

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Titlepage

Contents

Chapter 1 General Introduction.

Chapter 2 Strongly Nucleophilic Rh(I) Centres in Novel Square Planar Complexes with Terdentate (k3) 2,2':6'2"- Terpyridine Ligands: Crystallographic, Electrochemical and Density Functional Theoretical Studies.

Chapter 3 Oxidative Addition Reactions of [Rh1(Br)(Tpy*)](Tpy*=4'-(4-tbutylphenyl)-2,2':6',2"-terpyridine) with Alkyl Bromides.

Chapter 4 [Rh¹(Br)(2,2':6',2"-Terpyridine)]: Easy Access to the Synthesis of Neutral Octahedral Rh(III)-based Metallomesogens Displaying Lyotropic Mesomorphism with Dichloromethane.

Chapter 5 Crystal Structure of the Novel Neutral Octahedral Complex [Rhᴵᴵᴵ(Br)(Acetonyl)2(4'-(4-tButylphenyl)-2,2':6',2"-Terpyridine)].

Summary

Samenvatting

Appendix

Dankwoord

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