Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β-Aldehyde Intermediates
| Authors | |
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| Publication date | 02-04-2013 |
| Journal | Angewandte Chemie |
| Volume | Issue number | 125 | 14 |
| Pages (from-to) | 3970-3974 |
| Number of pages | 5 |
| Organisations |
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| Abstract | Go against the flow! A rationally designed regioselective hydroformylation catalyst, [Rh/L], in which noncovalent ligand–substrate interactions allow the unprecedented reversal of selectivity from the typical α‐aldehyde to the otherwise unfavored product β‐aldehyde, is reported. This catalytic system opens up novel and sustainable synthetic pathways to important intermediates for the fine‐chemicals industry. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Related publication | Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β-Aldehyde Intermediates |
| Published at | https://doi.org/10.1002/ange.201209582 https://doi.org/10.1002/anie.201209582 |
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