Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand
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| Publication date | 01-01-2017 |
| Journal | Chemistry-A European Journal |
| Volume | Issue number | 23 | 1 |
| Pages (from-to) | 33-37 |
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| Abstract | The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHPtBu2)2}] is reported. This compound exhibits reversible, ligand‐centered oxidation and protonation reactions. The resulting pincer chemical non‐innocence can be utilized for benzylic C−H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Related dataset | CCDC 1501124: Experimental Crystal Structure Determination CCDC 1501123: Experimental Crystal Structure Determination CCDC 1501125: Experimental Crystal Structure Determination CCDC 1501126: Experimental Crystal Structure Determination |
| Published at | https://doi.org/10.1002/chem.201604407 |
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