Phosphorus-Chiral ligands Based on Ferrocene: Stereoselective Synthesis and Application in Asymmeteric Catalysis.

Authors	U.A. Nettekoven
Supervisors	P.W.N.M. van Leeuwen
Cosupervisors	M. Widhalm P.C.J. Kamer
Award date	18-05-2000
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Document type	PhD thesis
Language	English
Downloads	Thesis Cover Titlepage Contents Chapter 1 General Introduction Chapter 2 Phosphorus-Chiral Analogues of 1,1'-Bis(diphenylphosphino)ferrocene: Asymmetric Synthesis and Application in Highly Enantioselective Rhodium-Catalyzed Hydrogenation Reactions Chapter 3 Diastereoselective ortho-Metalation of Stereogenic Ferrocenylphosphine Oxides. Asymmetric Synthesis of the First Enantiopure Phosphorus-Chiral 2,2'-Bis(diarylphosphino)-1,1'-biferrocenyls. Chapter 4 Phosphorus-Chiral Diphosphines as Ligands in Hydroformylation. An Investigation Towards the Influence of Electronic Effects in Catalysis. Chapter 5 Steric and Electronic Ligand Perturbations in Catalysis: Asymmetric Allylic Substitution Reactions Using C₂-Symmetrical Phosphorus-Chiral (Bi)Ferrocenyl Donors Summary and Evaluation Samenvatting Acknowledgement Cover
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