S,O-ligand-promoted palladium-catalyzed C–H olefination of arenes with allylic substrates
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| Publication date | 24-01-2018 |
| Journal | Tetrahedron Letters |
| Volume | Issue number | 59 | 4 |
| Pages (from-to) | 379-382 |
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| Abstract | An efficient catalytic system for the C–H olefination of arenes with different allylic substrates is reported. The catalytic system is based on Pd(OAc)2 and a readily accessible bidentate S,O-ligand. The methodology shows high activity with a wide range of arenes, including bulky and, electron-rich and -poor arenes. The applicability of this catalyst is demonstrated in the late-stage functionalization of the complex molecule O-methylestrone. |
| Document type | Article |
| Note | With supplementary material |
| Language | English |
| Published at | https://doi.org/10.1016/j.tetlet.2017.12.047 |
| Downloads |
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