Hypovalent substrates in transition metal catalysis: C-H bond functionalisation, ring-closing reactions &amp; polymer synthesis

Hypovalent substrates in transition metal catalysis: C-H bond functionalisation, ring-closing reactions & polymer synthesis

Authors	A.I. Olivos Suárez
Supervisors	J.N.H. Reek
Cosupervisors	B. de Bruin
Award date	04-06-2013
Number of pages	199
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Document type	PhD thesis
Note	Research conducted at: Universiteit van Amsterdam
Language	English
Downloads	Thesis Cover Title pages Table of contents Preface Chapter 1: Nitrogen-centred ligand radical complexes: Classification, spectroscopic features, reactivity and catalytic applications Chapter 2: The radical mechanism of cobalt(II) porphyrin-catalysed olefin aziridination and the importance of H–bonding Chapter 3: Mechanism of cobalt(II) porphyrin-catalysed C-H amination with organic azides: Radical nature and H–atom abstraction ability of the key cobalt(III)-nitrene intermediates Chapter 4: (Porphyrin)Fe-nitrene/imido intermediates from azides: Alternatives to the (por)Fe=NR high valent species Chapter 5: Towards controlled nitrene-transfer reactivity using Co and Fe porphyrin catalysts Chapter 6: Rh-mediated C1-polymerisation: Copolymers from diazoesters and sulfoxonium ylides Summary Samenvatting List of publications Acknowledgments
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