Robust Benzo[g,h,i]perylenetriimide Dye-Sensitized Electrodes in Air-Saturated Aqueous Buffer Solution
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| Publication date | 2016 |
| Journal | Chemistry - A European Journal |
| Volume | Issue number | 22 | 16 |
| Pages (from-to) | 5489-5493 |
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| Abstract | Highly electron deficient benzo[ghi]perylenetriimide (BPTI) chromophores were persistently anchored to a metal oxide electrode surface and reversible formation of their radical anions was shown in air-saturated aqueous buffer solution. Our results show a very low reaction-rate constant of BPTI.- with O-2 (k=1.92 +/- 0.05x10(-2)s(-1)). BPTI is a robust chromophore that can be used as the electron acceptor in molecule-based artificial photosynthetic devices for direct water splitting in aqueous phase. |
| Document type | Article |
| Note | With supporting information |
| Language | English |
| Published at | https://doi.org/10.1002/chem.201505146 |
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Robust Benzo[g,h,i]perylenetriimide
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