Electromeric Rhodium Radical Complexes
| Authors |
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|---|---|
| Publication date | 08-01-2010 |
| Journal | Angewandte Chemie |
| Volume | Issue number | 122 | 2 |
| Pages (from-to) | 395-399 |
| Number of pages | 5 |
| Organisations |
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| Abstract | Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P—Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the "red" complex has the highest spin density at Rh of all low valent Rh complexes observed to date. |
| Document type | Article |
| Note | Dedicated to Professor Martin Quack. - Correction published in: Volume 122, Issue 11, Angewandte Chemie, p. 1953-1953. - With supplementary files |
| Language | English |
| Related publication | Electromeric Rhodium Radical Complexes |
| Published at |
https://doi.org/10.1002/ange.200903201
(Final published version)
https://doi.org/10.1002/anie.200903201
(Other version)
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