Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex

Authors
  • M.E. Smith
  • E.L. Flynn
  • M.A. Fox
  • A. Trottier
  • E. Wrede
  • D.S. Yufit
  • J.A.K. Howard
  • K.L. Ronayne
  • M. Towrie
  • A.W. Parker
  • F. Hartl
  • P.J. Low
Publication date 2008
Journal Chemical Communications
Pages (from-to) 5845-5847
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}-(mu-C CC N){Re(CO)(3)(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.
Document type Article
Published at
https://doi.org/10.1039/b811357b (Final published version)
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