Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex
Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex
Authors
M.E. Smith
E.L. Flynn
M.A. Fox
A. Trottier
E. Wrede
D.S. Yufit
J.A.K. Howard
K.L. Ronayne
M. Towrie
A.W. Parker
F. Hartl
P.J. Low
Publication date
2008
Journal
Chemical Communications
Pages (from-to)
5845-5847
Organisations
Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract
Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}-(mu-C CC N){Re(CO)(3)(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.