CO₂Hydrogenation at Atmospheric Pressure and Low Temperature Using Plasma-Enhanced Catalysis over Supported Cobalt Oxide Catalysts

CO₂ is a promising renewable, cheap, and abundant C1 feedstock for producing valuable chemicals, such as CO and methanol. In conventional reactors, because of thermodynamic constraints, converting CO₂ to methanol requires high temperature and pressure, typically 250 °C and 20 bar. Nonthermal plasma is a better option, as it can convert CO₂ at near-ambient temperature and pressure. Adding a catalyst to such plasma setups can enhance conversion and selectivity. However, we know little about the effects of catalysts in such systems. Here, we study CO₂ hydrogenation in a dielectric barrier discharge plasma-catalysis setup under ambient conditions using MgO, γ-Al₂O₃, and a series of Co_xO_y/MgO catalysts. While all three catalyst types enhanced CO₂ conversion, Co_xO_y/MgO gave the best results, converting up to 35% of CO₂ and reaching the highest methanol yield (10%). Control experiments showed that the basic MgO support is more active than the acidic γ-Al₂O₃, and that MgO-supported cobalt oxide catalysts improve the selectivity toward methanol. The methanol yield can be tuned by changing the metal loading. Overall, our study shows the utility of plasma catalysis for CO₂ conversion under mild conditions, with the potential to reduce the energy footprint of CO₂-recycling processes.