Enhanced CO2 sorption and selectivity by functionalization of a NbO-type metal-organic framework with polarized benzothiadiazole moieties

Open Access
Authors
  • C. Song
  • Y. He
  • B. Li
  • Y. Ling
Publication date 2014
Journal Chemical Communications
Volume | Issue number 50 | 81
Pages (from-to) 12105-12108
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract A new NbO-type metal-organic framework ZJNU-40 incorporating highly polarized benzothiadiazole moieties exhibits a high CO2 uptake of 108 cm(3) g(-1) at 296 K and 1 atm, as well as good adsorption selectivities of CO2 over CH4 and N-2 at room temperature, which is superior to that of the analogous MOF NOTT-101.
Document type Article
Note With supplementary info
Language English
Published at https://doi.org/10.1039/c4cc05833j
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Enhanced CO2 sorption (Final published version)
Supplementary materials
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