A Co(TAML)-based artificial metalloenzyme for asymmetric radical-type oxygen atom transfer catalysis

Open Access
Authors
Publication date 21-12-2023
Journal Chemical Communications
Article number 14567
Volume | Issue number 59 | 98
Pages (from-to) 14567-14570
Number of pages 4
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract

We show that the incorporation of a biotinylated Co(TAML) cofactor within streptavidin enables asymmetric radical-type oxygen atom transfer catalysis with improved activity and enantioselectivity.
Document type Article
Note With supplementary material.
Language English
Published at https://doi.org/10.1039/d3cc04723g
Other links https://www.scopus.com/pages/publications/85178312893
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d3cc04723g (Final published version)
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