Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand

Activation of H₂ by a highly distorted Rh^II complex with a new C₃-symmetric tripodal tetraphosphine ligand

Authors	J. Wassenaar B. de Bruin M.A. Siegler A.L. Spek J.N.H. Reek J.I. van der Vlugt
Publication date	2010
Journal	Chemical Communications
Volume \| Issue number	46 \| 8
Pages (from-to)	1232-1234
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract	Facile oxidation of a sterically encumbered Rh(I) complex generates a stable Rh(II) metalloradical species; the latter is able to activate H2 under formation of the corresponding Rh(III) complex.
Document type	Article
Language	English
Published at	https://doi.org/10.1039/b917632b
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