Reversible multi-electron storage in dual-site redox-active supramolecular cages
| Authors |
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|---|---|
| Publication date | 28-10-2019 |
| Journal | Chemical Communications |
| Volume | Issue number | 55 | 84 |
| Pages (from-to) | 12619-12622 |
| Number of pages | 4 |
| Organisations |
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| Abstract | M6L412+ supramolecular cages 3a and 3b (M = Pd, Pt), soluble in organic solvents, contain two different ligand-centered redox sites that enable the reversible storage of up to 16 electrons, as probed by CV, UV/vis spectro-electrochemistry (SEC-UV/Vis), bulk electrolysis and EPR. Encapsulation of a B12F122− anion is confirmed by 1H, 19F NMR and 19F DOSY NMR spectroscopy and mass spectrometry. |
| Document type | Article |
| Note | With supplementary files |
| Language | English |
| Related dataset | CCDC 1923049: Experimental Crystal Structure Determination CCDC 1923050: Experimental Crystal Structure Determination |
| Published at | https://doi.org/10.1039/c9cc07138e |
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Reversible multi-electron storage in dual-site redox-active supramolecular cages
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