Selective P-4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides
| Authors |
|
|---|---|
| Publication date | 2014 |
| Journal | Chemical Communications |
| Volume | Issue number | 50 | 53 |
| Pages (from-to) | 7014-7016 |
| Organisations |
|
| Abstract | The reaction of the 17e nickel(I) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P-4 results in a nickel tetraphosphide [{CpNi(IDipp)}(2)(mu-eta(1):eta(1)-P-4)] with a butterfly-P-4(2)-ligand; related chalcogenides [{CpNi(IDipp)}(2)(mu-E-2)] (E = S, Se, Te) and [{CpNi(IDipp)}(2)(mu-E-3)] (E = S, Se) are formed with S-8, Se-infinity and Te-infinity. |
| Document type | Article |
| Language | English |
| Published at | https://doi.org/10.1039/c4cc02601b |
| Downloads | |
| Supplementary materials | |
| Permalink to this page | |
