[Ni(cod)2][Al(ORF)4], a source for naked nickel(I) chemistry

[Ni(cod)₂][Al(OR^F)₄], a source for naked nickel(I) chemistry

Authors	M.M. Schwab D. Himmel S. Kacprzak D. Kratzert V. Radtke P. Weis K. Ray E.W. Scheidt W. Scherer B. de Bruin S. Weber I. Krossing
Publication date	01-12-2015
Journal	Angewandte Chemie
Volume \| Issue number	127 \| 49
Pages (from-to)	14919-14922
Number of pages	4
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract	The straightforward synthesis of the cationic, purely organometallic Ni^I salt [Ni(cod)₂]⁺[Al(OR^F)₄]⁻ was realized through a reaction between [Ni(cod)₂] and Ag[Al(OR^F)₄] (cod=1,5‐cyclooctadiene). Crystal‐structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic Ni^I olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic Ni^I complexes.
Document type	Article
Note	With supplementary file
Language	English
Related publication	[Ni(cod)<sub>2</sub>][Al(OR<sup>F</sup>)<sub>4</sub>], a source for naked nickel(I) chemistry
Published at	https://doi.org/10.1002/ange.201506475 https://doi.org/10.1002/anie.201506475
Downloads	ange.201506475 (Final published version)
Supplementary materials	ange_201506475_sm_miscellaneous_information
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