| Authors |
|
| Publication date |
2010
|
| Journal |
Chemical Communications
|
| Volume | Issue number |
46 | 12
|
| Pages (from-to) |
2061-2063
|
| Organisations |
-
Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
|
| Abstract |
In rotaxane 1, two co-conformations are populated in CDCl3 at temperatures between 250 and 330 K. The thermodynamic parameters show strong enthalpy-entropy compensation, and a non-negligible heat capacity difference between the two forms.
|
| Document type |
Article
|
| Language |
English
|
| Published at |
https://doi.org/10.1039/b926868e
|
| Published at |
http://dx.doi.org/10.1039/B926868E
|
|
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