Palladium-catalyzed stereoselective hydrogenation of alkynes to (Z)-alkenes in common solvents and supercritical CO2

Thesis

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Titlepage

Table of Contents

1 General Introduction Organometallic Chemistry

2 Introduction into Supercritical Fluids and Experimental Setup

3 Synthesis and Characterization of CO₂-philic Ar-bian Ligands

4 Synthesis and Characterization of CO₂-philic Zerovalent Palladium Complexes; Use of Pd(nbd)(ma) as Precursor Complex§

5 Kinetic study and Spectroscopic Investigation of the semihydrogenation of 4-octyne catalyzed by Pd[(m,m'-(CF₃)₂C₆H₃) bian](ma) in THF

6 Stereoselective Hydrogenation of Alkynes in Supercritical CO₂

Summary

Samenvatting

Appendix I

Appendix II

Dankwoord

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