Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
| Authors |
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| Publication date | 28-09-2020 |
| Journal | Angewandte Chemie, International Edition |
| Volume | Issue number | 59 | 40 |
| Pages (from-to) | 17482-17487 |
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| Abstract | The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Related publication | Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements |
| Published at |
https://doi.org/10.1002/anie.202007814
(Final published version)
https://doi.org/10.1002/ange.202007814
(Other version)
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