(3+1) resonance enhanced multiphoton ionization-photoelectron spectroscopy on the E, F, and G Rydberg states of ClO

Open Access
Authors
Publication date 1996
Journal Chemical Physics Letters
Volume | Issue number 259 | 1-2
Pages (from-to) 213-218
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract (3 + 1) resonance enhanced multiphoton ionization-photoelectron spectroscopy is employed to investigate the spectroscopy and ionization dynamics of the E, F, and G Rydberg states of ClO. The results establish that the E and F Rydberg states converge upon the X3- ground ionic state, while the G state belongs to a Rydberg series with an excited a 1D ioni core. Improved ionization thresholds of these two ionic states are determined as 10.887 ± 0.005 and 11.750 ± 0.005 eV.
Document type Article
Language English
Published at https://doi.org/10.1016/0009-2614(96)00720-8
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ChPhL_1996_259_213.pdf (Final published version)
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