A simple building-block route to (phosphanyl-carbene)palladium complexes via intermolecular addition of functionalised phosphanes to isocyanides
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| Publication date | 2009 |
| Journal | European Journal of Inorganic Chemistry |
| Pages (from-to) | 1313-1316 |
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| Abstract | We present a straightforward protocol for making (phosphanyl-carbene)PdII complexes. These complexes have bidentate ligands containing an acyclic diamino- or aminooxy-carbene and a phosphane. The synthesis gives good yields (typically 70-90 %) for a variety of complexes (22 compounds). Moreover, it does not require the synthesis of imidazolium salts nor the a priori generation of free carbenes. Three of the new complexes were tested as catalysts for Sonogashira and Hay coupling reactions, with good yields and selectivities. |
| Document type | Article |
| Published at |
https://doi.org/10.1002/ejic.200801067
(Final published version)
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