Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides
| Authors |
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| Publication date | 2008 |
| Journal | Organometallics |
| Volume | Issue number | 27 | 13 |
| Pages (from-to) | 3210-3215 |
| Organisations |
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| Abstract | The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex. |
| Document type | Article |
| Language | English |
| Published at |
https://doi.org/10.1021/om800127h
(Final published version)
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