Supramolecular control of ligand coordination and implications in hydroformylation reactions
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| Publication date | 01-08-2011 |
| Journal | Angewandte Chemie |
| Volume | Issue number | 123 | 32 |
| Pages (from-to) | 7480-7483 |
| Number of pages | 4 |
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| Abstract | The coordination mode of a monodentate phosphoroamidite ligand in a rhodium complex can be switched from equatorial to axial by a unique supramolecular pseudo encapsulation (see scheme). The axial complex has higher activity and selectivity in the challenging asymmetric hydroformylation of internal alkenes. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Related publication | Supramolecular control of ligand coordination and implications in hydroformylation reactions |
| Published at | https://doi.org/10.1002/ange.201101653 https://doi.org/10.1002/anie.201101653 |
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