Stereospecific carbene polymerization with oxygenated Rh(diene) species
| Authors |
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|---|---|
| Publication date | 21-05-2012 |
| Journal | Angewandte Chemie, International Edition |
| Volume | Issue number | 51 | 21 |
| Pages (from-to) | 5157-5161 |
| Number of pages | 5 |
| Organisations |
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| Abstract |
Breath-taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII-polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2-rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Related publication | Stereospecific carbene polymerization with oxygenated Rh(diene) species |
| Published at |
https://doi.org/10.1002/anie.201200069
(Final published version)
https://doi.org/10.1002/ange.201200069
(Other version)
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| Permalink to this page | |
