Phosphacycle containing ligands : metal complexes and catalysis

Thesis

Cover

Title pages

Table of contents

Chapter 1: General introduction

Chapter 2: P-chirogenic benzo-fused phenoxaphosphane : synthesis, resolution and study of the stereo-chemical properties of the corresponding palladium complexes

Chapter 3: A triarylphosphane in its three covalently locked conformations : the construction of an empirical stereo-model

Chapter 4: A case study on substrate pre-organization in the rhodium catalyzed asymmetric hydroformylation reaction

Chapter 5: P,O ligands in the nickel-catalyzed oligomerization reaction of ethene and palladium-catalyzed asymmetric hydrovinylation of styrene

Appendix: Conformationally diverse square planar Rh(I) complexes : analysis of the coordination chemical shift (∆P)

Summary

Samenvatting

Acknowledgements