Self-assembly of a confined rhodium catalyst for asymmetric hydroformylation of unfunctionalized internal alkenes
| Authors |
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| Publication date |
2012
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| Journal |
Journal of the American Chemical Society
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| Volume | Issue number |
134 | 6
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| Pages (from-to) |
2860-2863
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| Organisations |
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Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
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Faculty of Science (FNWI) - Swammerdam Institute for Life Sciences (SILS)
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| Abstract |
A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes. Spatial confinement of the metal center within a chiral pocket results in reversed regioselectivity and remarkable enantioselectivities.
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| Document type |
Article
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| Language |
English
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| Published at |
https://doi.org/10.1021/ja211455j
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