P-N Bridged Dinuclear Rh-METAMORPhos Complexes: NMR and Computational Studies
| Authors |
|
|---|---|
| Publication date | 09-09-2018 |
| Journal | European Journal of Inorganic Chemistry |
| Volume | Issue number | 2018 | 33 |
| Pages (from-to) | 3761-3769 |
| Number of pages | 9 |
| Organisations |
|
| Abstract | Sulfonamido‐phosphoramidites are known to form six‐membered ring Rh‐P‐N‐Rh‐P‐N‐ dinuclear complexes. Apart from a single X‐ray structure, little is known about their three dimensional structure in solution. This study proposes a 31P, 15N and 103Rh NMR investigation of the question, as a well as a DFT study. The AA′MM′XX′ 6 spin system of the corresponding 15N‐enriched dinuclear complex is notably described. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Published at | https://doi.org/10.1002/ejic.201800397 |
| Downloads |
Patureau_et_al-2018-European_Journal_of_Inorganic_Chemistry
(Final published version)
|
| Supplementary materials | |
| Permalink to this page | |