Facile Synthesis of Tuneable Azophosphonium Salts
| Authors |
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|---|---|
| Publication date | 31-03-2019 |
| Journal | European Journal of Inorganic Chemistry |
| Volume | Issue number | 2019 | 11-12 |
| Pages (from-to) | 1594-1603 |
| Number of pages | 10 |
| Organisations |
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| Abstract | Azophosphonium salts have a facile synthesis and can be readily tuned at the para position of the aryl group and at the phosphorus position with the use of bulky phosphines, leading to a range of coloured compounds. A relation between the Hammett σ+para constant and the colour and 31P NMR chemical shift was explored. The compounds were characterised by NMR spectroscopy, UV/Vis spectroscopy and single‐crystal X‐ray structure crystallography. |
| Document type | Article |
| Note | -In Special Issue: Phosphorus Chemistry. - With supplementary file |
| Language | English |
| Related dataset | CCDC 1866249: Experimental Crystal Structure Determination CCDC 1866248: Experimental Crystal Structure Determination CCDC 1866247: Experimental Crystal Structure Determination |
| Published at | https://doi.org/10.1002/ejic.201801546 |
| Downloads |
ejic.201801546
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