Indole-based phosphorus ligands in asymmetric catalysis

Authors	J. Wassenaar
Supervisors	J.N.H. Reek
Award date	30-06-2010
Number of pages	171
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Document type	PhD thesis
Note	Cum laude. Research conducted at: Universiteit van Amsterdam
Language	English
Downloads	Thesis Front cover Title pages Table of contents Chapter 1: Phosphorus ligands in asymmetric catalysis: a general introduction Chapter 2: IndolPhos: novel hybrid phosphine-phosphoramidite for asymmetric hydrogenation and hydroformylation Chapter 3: Asymmetric synthesis of the Roche Ester and its derivatives by Rh-IndolPhos catalyzed hydrogenation Chapter 4: Asymmetric hydrogenation of enamides, α-enol and α-enamido ester phosphonates catalyzed by IndolPhos-Rh complexes Chapter 5: Asymmetric hydrogenation with highly active IndolPhos-Rh catalysts: kinetics and reaction mechanism Chapter 6: Rh-catalyzed asymmetric hydroformylation with Taddol-based IndolPhos ligands Chapter 7: IndolPhosphole and IndolPhos palladium-allyl complexes in asymmetric allylic alkylations Chapter 8: Survival of the weakest: catalyst selection based on intermediate stability measured by mass spectrometry Chapter 9: Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand Summary Samenvatting List of publications Dankwoord
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