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Author
T. Zaharia
A.W. Kleyn
M.A. Gleeson
Year
2014
Title
Eley-Rideal Reactions with N Atoms at Ru(0001): Formation of NO and N-2
Journal
Physical Review Letters
Volume | Issue number
113 | 5
Pages (from-to)
053201
Number of pages
5
Document type
Article
Faculty
Faculty of Science (FNWI)
Institute
Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract
Forward-directed NO molecules with large translational energies are formed upon exposure of an O-covered Ru(0001) surface to a nitrogen (N + N-2) beam. This is an unequivocal experimental demonstration of the Eley-Rideal reaction for a "heavy" (i.e., nonhydrogenated) neutral system. The time dependence of prompt NO formation exhibits an exceptionally fast decay as a consequence of shifting reaction pathways and probabilities over the course of the exposure. Prompt production shuts down as the O coverage decreases due to competition from more favorable Eley-Rideal production of N-2.
URL
go to publisher's site
Language
English
Permalink
http://hdl.handle.net/11245/1.432862
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  • Eley-Rideal Reactions with N Atoms

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