C.A. de Lange
- (3+1) resonance enhanced multiphoton ionization-photoelectron spectroscopy on the E, F, and G Rydberg states of ClO
- Chemical Physics Letters
- Volume | Issue number
- 259 | 1-2
- Pages (from-to)
- Document type
- Faculty of Science (FNWI)
- Van 't Hoff Institute for Molecular Sciences (HIMS)
- (3 + 1) resonance enhanced multiphoton ionization-photoelectron spectroscopy is employed to investigate the spectroscopy and ionization dynamics of the E, F, and G Rydberg states of ClO. The results establish that the E and F Rydberg states converge upon the X3- ground ionic state, while the G state belongs to a Rydberg series with an excited a 1D ioni core. Improved ionization thresholds of these two ionic states are determined as 10.887 ± 0.005 and 11.750 ± 0.005 eV.
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