B. de Bruin
- Electromeric rhodium radical complexes
- Angewandte Chemie, International Edition
- Volume | Issue number
- 49 | 2
- Pages (from-to)
- Document type
- Faculty of Science (FNWI)
- Van 't Hoff Institute for Molecular Sciences (HIMS)
- Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P—Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the "red" complex has the highest spin density at Rh of all low valent Rh complexes observed to date.
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