- Functionalization of P4 through Direct P-C Bond Formation
- CHEMISTRY-A EUROPEAN JOURNAL
- Volume | Issue number
- 23 | 49
- Pages (from-to)
- Document type
- Faculty of Science (FNWI)
- Van 't Hoff Institute for Molecular Sciences (HIMS)
Institute of Interdisciplinary Studies (ISS)
Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track record, but methods that allow desirable, direct P-C bond formations have only recently emerged. These include the use of metal organyls, carbenes, carboradicals, and photochemical approaches. The versatile product scope enables the preparation of both industrially relevant organophosphorus compounds, as well as a broad range of intriguing new compound classes. Herein we provide a concise overview of recent breakthroughs and outline the acquired fundamental insights to aid future developments.
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