Authors
Felix Schneck
Markus Finger
Moniek Tromp
Sven Schneider
Date (dd-mm-yyyy)
2017-01-01
Title
Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand
Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume
23
Publication Year
2017-01-01
Pages
33-37
Issue number
1
Document type
Article
Faculty
Faculty of Science (FNWI)
Institute
Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract
The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHPtBu2)(2)}] is reported. This compound exhibits reversible, ligand-centered oxidation and protonation reactions. The resulting pincer chemical non-innocence can be utilized for benzylic C-H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined.
URL
go to publisher's site
Permalink
https://hdl.handle.net/11245.1/d4e5be5b-a2a1-45d2-933e-69ef5070ffd3