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Zoekopdracht: faculteit: "FNWI" en publicatiejaar: "2010"

AuteursT.N. Raja, A.M. Brouwer, K. Biemans, T. Nabuurs, R. Tennebroek
TitelDetection of coalescing agents in water-borne latex emulsions using an environment sensitive fluorescent probe
TijdschriftPhotochemical & Photobiological Sciences
Jaargang9
Jaar2010
Nummer7
Pagina's975-984
ISSN1474905X
FaculteitFaculteit der Natuurwetenschappen, Wiskunde en Informatica
Instituut/afd.FNWI: Van 't Hoff Institute for Molecular Sciences (HIMS)
SamenvattingIn this paper we report the determination of partitioning of coalescing agents (organic co-solvents) in water-borne latex emulsions by means of a fluorescence method. An environment-sensitive fluorescent probe 1 was copolymerized via emulsion polymerization. The presence of organic co-solvents inside the polymer particles is revealed by the photophysical properties of the probe. In particular, the position of the fluorescence emission maximum of co-polymerized 1 can be used to measure the amount of coalescing agent present in the polymer particles. The spectral shifts are shown to be due to the softening of the matrix, rather than to solvation of the probe by the added co-solvent.
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