The UvA-LINKER will give you a range of other options to find the full text of a publication (including a direct link to the full-text if it is located on another database on the internet).
De UvA-LINKER biedt mogelijkheden om een publicatie elders te vinden (inclusief een directe link naar de publicatie online als deze beschikbaar is in een database op het internet).

Zoekresultaten

Zoekopdracht: faculteit: "FNWI" en publicatiejaar: "2009"

AuteursJ.D. Steill, J. Oomens
TitelGas-phase deprotonation of p-hydroxybenzoic acid investigated by IR spectroscopy: Solution-phase structure is retained upon ESI
TijdschriftJournal of the American Chemical Society
Jaargang131
Jaar2009
Nummer38
Pagina's13570-13571
ISSN00027863
FaculteitFaculteit der Natuurwetenschappen, Wiskunde en Informatica
Instituut/afd.FNWI: Van 't Hoff Institute for Molecular Sciences (HIMS)
SamenvattingThe gas-phase structure of the conjugate base of p-hydroxybenzoic acid (and related compounds) and the influence of the solvent used in its generation by electrospray ionization have recently been under debate. While the phenoxide structure is known to be lower in energy in the gas phase, the carboxylate structure is favored in aqueous solution, fuelling the controversy. Here we probe the structure of this gas-phase anion by IR spectroscopy and show that its structure is determined by the protic or aprotic nature of the solvent, which suggests that it is the solution-phase structure that is transferred to the gas phase.
Soort documentArtikel
Document finderUvA-Linker