The UvA-LINKER will give you a range of other options to find the full text of a publication (including a direct link to the full-text if it is located on another database on the internet).
De UvA-LINKER biedt mogelijkheden om een publicatie elders te vinden (inclusief een directe link naar de publicatie online als deze beschikbaar is in een database op het internet).

Zoekresultaten

Zoekopdracht: faculteit: "FNWI" en publicatiejaar: "2003"

AuteursP.B. Glover, P.R. Ashton, L.J. Childs, A. Rodger, M. Kercher, R.M. Williams, L. De Cola, Z. Pikramenou
TitelHairpin-shaped heterometallic luminescent lanthanide complexes for DNA intercalative recognition
TijdschriftJournal of the American Chemical Society
Jaargang125
Jaar2003
Nummer33
Pagina's9918-9919
ISSN00027863
FaculteitFaculteit der Natuurwetenschappen, Wiskunde en Informatica
Instituut/afd.FNWI: Van 't Hoff Institute for Molecular Sciences (HIMS)
Trefwoordenliquid crystals; DNA; ligands; platinum; catalysts
Basisclassificatie35.53 ; 35.60
SamenvattingLuminescent Ln-Pt2 metallohairpin complexes have been developed, and their intercalative recognition with DNA has been demonstrated with linear dichroism spectroscopy. The heterotrimetallic complexes were formed in a one-step reaction, by assembly of an aminopolycarboxylate ligand, a platinum terpyridine unit, and the lanthanide salt. The metallohairpin complexes bear a neutral lanthanide moiety and two positively charged platinum-containing intercalating units. The Nd(III) analogues are luminescent in the near infrared, and this near-IR luminescence is retained upon binding to DNA. The DNA recognition was demonstrated by linear dichroism spectroscopy. The linear dichroism spectra suggested that the complexes bind perpendicular to the DNA helical axis, confirming intercalative recognition accompanied by dramatic stiffening of DNA, which suggests bis-intercalation of the complex.
Soort documentArtikel
Document finderUvA-Linker