Zoekopdracht:
faculteit: "FNWI" en publicatiejaar: "1997"
| Auteurs | J.B. Milan, W.J. Buma, C.A. de Lange, K. Wang, V. McKoy | | Titel | Rotationally resolved multiphoton ionization photoelectron spectroscopy of the [a 1D]3dp 2F and [a 1D]5pp 2F Rydberg states of the SH radical |
| Tijdschrift | The Journal of Chemical Physics |
| Jaargang | 107 |
| Jaar | 1997 |
| Nummer | 8 |
| Pagina's | 2782-2792 |
| ISSN | 00219606 |
| Faculteit | Faculteit der Natuurwetenschappen, Wiskunde en Informatica |
| Instituut/afd. | FNWI: Van 't Hoff Institute for Molecular Sciences (HIMS) |
| Trefwoorden | Rydberg states; mercapto radical; ab initio calculations; REMPI-PES |
| Basisclassificatie | 33.33 ; 35.11 ; 35.25 |
| Samenvatting | Experimental and theoretical results on the rotationally resolved photoelectron spectra of the [a 1]3d 2(v = 0) and the [a 1]5p 2(v = 0) Rydberg states of the SH radical are presented. In particular, for the former state, ionization via a large number of members of different rotational branches is considered. The interplay between experiment and ab initio calculations, including alignment, allows for a detailed interpretation of the results. Asymmetries apparent in the rotational ionic distributions and the observed suppression of transitions involving a large change in angular momentum can be explained on the basis of the theory. ©1997 American Institute of Physics. |
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