Zoekopdracht:
faculteit: "FNWI" en publicatiejaar: "1993"
| Auteurs | W.J. Buma, E. de Beer, C.A. de Lange | | Titel | Resonance enhanced multiphoton ionization photoelectron spectroscopy and pulsed field ionization via the F 1D2(v'=0) and f 3D2(v'=0) Rydberg states of HCl |
| Tijdschrift | Journal of Chemical Physics |
| Jaargang | 99 |
| Jaar | 1993 |
| Nummer | 5 |
| Pagina's | 3252-3261 |
| ISSN | 00219606 |
| Faculteit | Faculteit der Natuurwetenschappen, Wiskunde en Informatica |
| Instituut/afd. | FNWI: Van 't Hoff Institute for Molecular Sciences (HIMS) |
| Trefwoorden | hydrogen chloride; Rydberg states; REMPI-PES; ab inition calculations |
| Basisclassificatie | 33.33 ; 35.11 |
| Samenvatting | In this paper, we report the first rotationally resolved one- and two-color resonance enhanced multiphoton ionization photoelectron spectroscopy (REMPI-PES) study of the HCl molecule. The agreement between our experimental branching ratios and theoretical investigations is excellent. We also report the first zero kinetic energy pulsed field ionization (ZEKE-PFI) experiments carried out in a "magnetic bottle'' electron spectrometer. A direct comparison is made between ZEKE-PFI and REMPI-PES spectra for ionization via several rotational levels of the F 12(v'=0) and f 32(v'=0) Rydberg states of HCl. Large differences in both the spin-orbit and rotational branching ratios are found between the ZEKE-PFI and REMPI-PES spectra. These differences can be understood qualitatively on the basis of rotational and spin-orbit autoionization mechanisms. The Journal of Chemical Physics is copyrighted by The American Institute of Physics. |
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